Flexibility and lability of a phenyl ligand in hetero-organometallic 3d metal–Sn(iv) compounds and their catalytic activity in Baeyer–Villiger oxidation of cyclohexanone-Reference-Cited by-同舟云学术

Flexibility and lability of a phenyl ligand in hetero-organometallic 3d metal–Sn(iv) compounds and their catalytic activity in Baeyer–Villiger oxidation of cyclohexanone

Published:2017 Issue:39 Volume:46 Page:13364-13375
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Hazra Susanta¹²³⁴⁵^ORCID,Martins Nuno M. R.¹²³⁴⁵^ORCID,Kuznetsov Maxim L.¹²³⁴⁵^ORCID,Guedes da Silva M. Fátima C.¹²³⁴⁵^ORCID,Pombeiro Armando J. L.¹²³⁴⁵^ORCID

Affiliation:

1. Centro de Química Estrutural

2. Instituto Superior Técnico

3. Universidade de Lisboa

4. Lisbon

5. Portugal

Abstract

An intermetallic Ph-shift (Sn^IV-to-Co^III) leads to a Co^III(Ph)–Sn^IV(Ph) and a mononuclear Co^III(Ph) compounds, while a M⋯π(Ph) interaction in the Ni^II/Cu^II–Sn^IV systems represents an intermediate stage of that Ph-shift.

Funder

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT02534C

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