What is the role of acid–acid interactions in asymmetric phosphoric acid organocatalysis? A detailed mechanistic study using interlocked and non-interlocked catalysts-Reference-Cited by-同舟云学术

What is the role of acid–acid interactions in asymmetric phosphoric acid organocatalysis? A detailed mechanistic study using interlocked and non-interlocked catalysts

Published:2020 Issue:17 Volume:11 Page:4381-4390
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Jansen Dennis¹²³⁴⁵,Gramüller Johannes⁶⁷⁸⁵,Niemeyer Felix¹²³⁴⁵^ORCID,Schaller Torsten¹²³⁴⁵^ORCID,Letzel Matthias C.⁹¹⁰¹¹⁵^ORCID,Grimme Stefan¹²¹³¹⁴⁵^ORCID,Zhu Hui¹²¹³¹⁴⁵,Gschwind Ruth M.⁶⁷⁸⁵^ORCID,Niemeyer Jochen¹²³⁴⁵^ORCID

Affiliation:

1. Faculty of Chemistry (Organic Chemistry) and Center for Nanointegration Duisburg-Essen (CENIDE)

2. University of Duisburg-Essen

3. Universitätsstrasse 7

4. 45141 Essen

5. Germany

6. Organic Chemistry

7. University of Regensburg

8. 93040 Regensburg

9. Institute of Organic Chemistry

10. University of Münster

11. 48149 Münster

12. Mulliken Center for Theoretical Chemistry

13. Rheinische Friedrich-Wilhelms Universität Bonn

14. 53115 Bonn

Abstract

Supramolecular acid–acid interactions lead to competing monomeric and dimeric pathways in phosphoric acid catalysis – so that stereoselectivities depend on catalyst concentration.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC01026J

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3. A Highly Enantioselective Brønsted Acid Catalyzed Cascade Reaction: Organocatalytic Transfer Hydrogenation of Quinolines and their Application in the Synthesis of Alkaloids

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5. On- and Off-Cycle Catalyst Cooperativity in Anion-Binding Catalysis

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