Molecular structure and spectroscopic properties of a nickel-bridged {Ni(Ph3P)}2(μ2–η2, η2-C60)2 dimer-Reference-Cited by-同舟云学术

Molecular structure and spectroscopic properties of a nickel-bridged {Ni(Ph3P)}2(μ2–η2, η2-C60)2 dimer

Published:2014 Issue:48 Volume:43 Page:17920-17923
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Konarev Dmitri V.¹²,Troyanov Sergey I.³⁴⁵,Nakano Yoshiaki⁶⁷⁸,Otsuka Akihiro⁶⁷⁸,Yamochi Hideki⁶⁷⁸,Saito Gunzi⁹¹⁰¹¹,Lyubovskaya Rimma N.¹²

Affiliation:

1. Institute of Problems of Chemical Physics RAS

2. Chernogolovka, Russia

3. Chemistry Department

4. Moscow State University

5. 119991 Moscow, Russia

6. Research Center for Low Temperature and Materials Sciences

7. Kyoto University

8. Kyoto 606-8501, Japan

9. Faculty of Agriculture

10. Meijo University

11. Nagoya 468-8502, Japan

Abstract

A nickel-bridged fullerene dimer, {Ni(Ph₃P)}₂(μ₂–η², η²-C₆₀)₂, was obtained and studied by X-ray crystallography. Optical and EPR spectra indicated a zero-valent state of Ni and no charge transfer from Ni to C₆₀.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT02161D

Reference16 articles.

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