Reactivity of cationic α-diimine cyclopentadienyl nickel complexes towards AlEt2Cl: synthesis, characterisation and ethylene polymerisation-Reference-Cited by-同舟云学术

Reactivity of cationic α-diimine cyclopentadienyl nickel complexes towards AlEt2Cl: synthesis, characterisation and ethylene polymerisation

Published:2017 Issue:14 Volume:7 Page:3128-3142
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Gomes Clara S. B.¹²³⁴⁵,Ribeiro Alejandro F. G.¹²³⁴⁵,Fernandes Anabela C.¹²³⁴⁵,Bento Artur¹²³⁴⁵,Rosário Ribeiro M.¹²³⁴⁵,Kociok-Köhn Gabriele⁶⁷⁸⁹,Pascu Sofia I.⁶⁷⁸⁹,Duarte M. Teresa¹²³⁴⁵^ORCID,Gomes Pedro T.¹²³⁴⁵^ORCID

Affiliation:

1. Centro de Química Estrutural

2. Departamento de Engenharia Química

3. Instituto Superior Técnico

4. Universidade de Lisboa

5. 1049-001 Lisboa

6. Chemistry Department

7. University of Bath

8. Bath

9. UK

Abstract

Cationic α-diimine cyclopentadienyl nickel complexes transform into intermediates upon reaction with AlEt₂Cl giving rise to active ethylene polymerisation catalysts.

Funder

Engineering and Physical Sciences Research Council

Science and Technology Facilities Council

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CY/C7CY00875A

Reference68 articles.

1. Cationic nickel and palladium complexes with bidentate ligands for the CC linkage of olefins