Characterization of two photon excited fragment spectroscopy (TPEFS) for HNO3 detection in gas-phase kinetic experiments-Reference-Cited by-同舟云学术

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Characterization of two photon excited fragment spectroscopy (TPEFS) for HNO3 detection in gas-phase kinetic experiments

Published:2021 Issue:11 Volume:23 Page:6397-6407
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Amedro Damien¹²³,Bunkan Arne J. C.¹²³,Dillon Terry J.¹²³,Crowley John N.¹²³^ORCID

Affiliation:

1. Division of Atmospheric Chemistry, Max Planck-Institut für Chemie

2. Mainz

3. Germany

Abstract

We have characterised two-photon excited fragment spectroscopy (TPEFS) for detecting HNO₃ and demonstrated its application in real-time kinetic studies by monitoring HNO₃ formation in the reaction of OH + NO₂ and deriving the rate coefficient.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP00297J

Reference59 articles.

1. Evaluated kinetic and photochemical data for atmospheric chemistry: Volume I - gas phase reactions of Ox, HOx, NOx and SOx species

2. Photodissociation of HNO3 at 193, 222, and 248 nm: Products and quantum yields

3. Photodissociation of nitric acid in a cold molecular beam at 193 nm

4. Quantum yields for OH production from 193 and 248 nm photolysis of HNO3 and H2O2

5. The influence of local electronic character and nonadiabaticity in the photodissociation of nitric acid at 193 nm

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