Electrochemical oxidative selenocyclization of olefinic amides towards the synthesis of iminoisobenzofurans

Author:

Li Hao1,Lu Fangling1,Xu Jie1,Hu Jianguo1,Alhumade Hesham23,Lu Lijun4,Lei Aiwen145ORCID

Affiliation:

1. National Research Center for Carbohydrate Synthesis, Jiangxi Normal University, Nanchang, Jiangxi 330022, P. R. China

2. Department of Chemical and Materials Engineering, Faculty of Engineering, King Abdulaziz University, Jeddah, Saudi Arabia

3. Center of Research Excellence in Renewable Energy and Power Systems, King Abdulaziz University, Jeddah, Saudi Arabia

4. Institute for Advanced Studies (IAS), College of Chemistry and Molecular Sciences, Engineering Research Center of Organosilicon Compounds & Materials (Ministry of Education), Wuhan University, Wuhan, Hubei 430072, P. R. China

5. King Abdulaziz University, Jeddah, Saudi Arabia

Abstract

We introduced an electrochemical oxidative radical cascade cyclization of olefinic amides and diselenides without a transition-metal catalyst and external oxidant. This selenocyclization reaction provided a facile method to construct C–Se and C–O bonds in one step.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Hubei Province

National Key Research and Development Program of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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