Spin state solvomorphism in a series of rare S = 1 manganese(iii) complexes

Author:

Barker Andrew1234,Kelly Conor T.1234ORCID,Kühne Irina A.1234ORCID,Hill Stephen56789ORCID,Krzystek J.5678ORCID,Wix Paul1011121314ORCID,Esien Kane1516171819,Felton Solveig1516171819ORCID,Müller-Bunz Helge1234,Morgan Grace G.1234ORCID

Affiliation:

1. School of Chemistry

2. University College Dublin (UCD)

3. Dublin 4

4. Ireland

5. National High Magnetic Field Laboratory

6. Florida State University

7. Tallahassee

8. USA

9. Department of Physics

10. School of Chemistry & CRANN Institute

11. Trinity College Dublin

12. University of Dublin

13. College Green

14. Dublin 2

15. Centre for Nanostructured Media (CNM)

16. School of Mathematics and Physics

17. Queen's University Belfast

18. Belfast, BT7 1NN

19. UK

Abstract

Structural, magnetic and spectroscopic data on four new spin triplet Mn3+ complexes reveals a large magnetic anisotropy. Spin state is sensitive to lattice contents as the spin quintet ground state is stabilized on co-crystallization with ethanol.

Funder

Science Foundation Ireland

Irish Research Council

U.S. Department of Energy

European Cooperation in Science and Technology

University College Dublin

National Science Foundation

Royal Society of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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