Evaluation of the microstructure, optical properties and hopping conduction mechanism of rare earth doped Ba0.85Ca0.12RE0.03Ti0.90Zr0.04Nb0.042O3 ceramics (RE = Ce3+ and Pr3+)

Author:

Bourguiba M.12,Raddaoui Z.34ORCID,Dimassi W.5,Chafra M.1,Dhahri J.3ORCID,Marchet P.4,Garcia M. A.6

Affiliation:

1. Laboratory of Applied Mechanics and Systems, School Polytechnic of Tunisia, University of Carthage, La Marsa, Tunisia

2. Faculty of Sciences Tunis, University of Tunis El Manar, Tunis 2092, Tunisia

3. Laboratory of Condensed Matter and Nanosciences, Faculty of Sciences of Monastir, University of Monastir, Avenue of the Environment, 5019 Monastir, Tunisia

4. Institute for Research on Ceramics, University of Limoges, UMR 7315, 87068 Limoges, France

5. Laboratory of Nanomaterials and Systems for Renewable Energies (LaNSER), Research and Technology Center of Energy, Techno-Park Borj-Cedria, Hammam-Lif 2050, Tunisia

6. Spanish National Research Counsil CSIC, Madrid, Spain

Abstract

This work examines the impact of rare earth (RE3+) ion substitution on the structural, optical and conduction properties of a Ba0.85Ca0.12RE0.03Ti0.90Zr0.04Nb0.042O3 (BCRETZN) (RE = Ce, Pr) ceramic compound produced via a solid-state route.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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