Fine-tuned organic photoredox catalysts for fragmentation-alkynylation cascades of cyclic oxime ethers
Author:
Affiliation:
1. Laboratory of Catalysis and Organic Synthesis
2. Institut des Sciences et Ingénierie Chimique
3. Ecole Polytechnique Fédérale de Lausanne
4. Lausanne
5. Switzerland
6. Laboratory for Computational Molecular Design
Abstract
Fine-tuned organic photoredox catalysts are introduced for the metal-free alkynylation of alkylnitrile radicals generated via oxidative ring opening of cyclic alkylketone oxime ethers.
Funder
H2020 European Research Council
Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung
FP7 Ideas: European Research Council
École Polytechnique Fédérale de Lausanne
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC01818A
Reference48 articles.
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3. Cascade Reactions in Total Synthesis
4. Radicals: Reactive Intermediates with Translational Potential
5. Photoredox Catalysis in Organic Chemistry
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