Heterobimetallic Pd/Mn and Pd/Co complexes as efficient and stereoselective catalysts for sequential Cu-free Sonogashira coupling–alkyne semi-hydrogenation reactions

Author:

Clauss Reike1ORCID,Baweja Saral1ORCID,Gelman Dmitri2ORCID,Hey-Hawkins Evamarie1ORCID

Affiliation:

1. Faculty of Chemistry and Mineralogy, Institute of Inorganic Chemistry, Leipzig University, Johannisallee 29, D-04103 Leipzig, Germany

2. Institute of Chemistry, The Hebrew University of Jerusalem, Jerusalem, 91904, Israel

Abstract

A series of heterobimetallic PdII/MII complexes (MII = Mn, Co) were synthesised and tested as precatalysts for sequential Sonogashira coupling–alkyne semi-hydrogenation reactions to form Z-aryl alkenes in a one-pot fashion.

Funder

Sächsische Aufbaubank

European Social Fund

German-Israeli Foundation for Scientific Research and Development

Graduate School BuildMoNa

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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