A visible-light mediated ring opening reaction of alkylidenecyclopropanes for the generation of homopropargyl radicals-Reference-Cited by-同舟云学术

A visible-light mediated ring opening reaction of alkylidenecyclopropanes for the generation of homopropargyl radicals

Published:2021 Issue: Volume: Page:
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Zhang Xiao-Yu¹²³⁴⁵,Ning Chao¹²³⁴⁵,Mao Ben¹²³⁴⁵,Wei Yin⁶⁷⁸⁹¹⁰^ORCID,Shi Min¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory for Advanced Materials and Institute of Fine Chemicals

2. Key Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center

3. School of Chemistry & Molecular Engineering

4. East China University of Science and Technology

5. Shanghai

6. State Key Laboratory of Organometallic Chemistry

7. Shanghai Institute of Organic Chemistry

8. Chinese Academy of Sciences

9. Shanghai 200032

10. China

Abstract

A non-classical ring opening radical clock reaction using the innovative NHPI esters bearing alkylidenecyclopropanes upon photoredox catalysis has been demonstrated, providing a brand-new synthetic approach to access a variety of alkynyl derivatives.

Funder

National Natural Science Foundation of China

Chinese Academy of Sciences

Science and Technology Commission of Shanghai Municipality

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC01889B

Reference57 articles.