The effect of thionation of the carbonyl group on the photophysics of compact spiro rhodamine-naphthalimide electron donor–acceptor dyads: intersystem crossing, charge separation, and electron spin dynamics-Reference-Cited by-同舟云学术

The effect of thionation of the carbonyl group on the photophysics of compact spiro rhodamine-naphthalimide electron donor–acceptor dyads: intersystem crossing, charge separation, and electron spin dynamics

Published:2023 Issue:46 Volume:25 Page:31667-31682
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Xiao Xiao¹^ORCID,Mu Tong¹^ORCID,Sukhanov Andrey A.²,Zhou Yihang¹,Yu Peiran¹^ORCID,Yu Fabiao³^ORCID,Elmali Ayhan⁴,Zhao Jianzhang¹^ORCID,Karatay Ahmet⁴,Voronkova Violeta K.²

Affiliation:

1. State Key Laboratory of Fine Chemicals, Frontier Science Center for Smart Materials, School of Chemical Engineering, Dalian University of Technology, 2 Ling Gong Rd., Dalian 116024, P. R. China

2. Zavoisky Physical-Technical Institute FRC Kazan Scientific Center of RAS, Sibirsky Tract 10/7, Kazan 420029, Russia

3. Key Laboratory of Hainan Trauma and Disaster Rescue, The First Affiliated Hospital of Hainan Medical University, Hainan Medical University, Haikou 571199, P. R. China

4. Department of Engineering Physics, Faculty of Engineering, Ankara University, 06100, Ankara, Turkey

Abstract

A long-lived charge transfer state (lifetime: 0.21 μs) was obtained in compact rhodamine-thionated naphthalimide electron donor–acceptor dyads via electron spin control.

Funder

Fundamental Research Funds for the Central Universities

National Natural Science Foundation of China

Dalian University of Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D3CP04891H

Reference110 articles.

1. Fullerenes: three dimensional electron acceptor materials

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5. Enhanced Intersystem Crossing via a High Energy Charge Transfer State in a Perylenediimide−Perylenemonoimide Dyad

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