Exploiting solid-state dynamic nuclear polarization NMR spectroscopy to establish the spatial distribution of polymorphic phases in a solid material-Reference-Cited by-同舟云学术

Exploiting solid-state dynamic nuclear polarization NMR spectroscopy to establish the spatial distribution of polymorphic phases in a solid material

Published:2023 Issue:37 Volume:14 Page:10121-10128
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Cousin Samuel F.¹^ORCID,Hughes Colan E.²^ORCID,Ziarelli Fabio³^ORCID,Viel Stéphane¹⁴^ORCID,Mollica Giulia¹^ORCID,Harris Kenneth D. M.²^ORCID,Pinon Arthur C.⁵,Thureau Pierre¹^ORCID

Affiliation:

1. Aix Marseille Univ, CNRS, ICR, Marseille, France

2. School of Chemistry, Cardiff University, Park Place, Cardiff CF10 3AT, Wales, UK,

3. Aix Marseille Univ, CNRS, Centrale Marseille, FSCM, Marseille, France

4. Institut Universitaire de France, Paris, France

5. Swedish NMR Center, University of Gothenburg, Gothenburg, SE-405 30, Sweden

Abstract

Solid-state DNP NMR is applied to detect a small amount of a minor polymorph of an organic material within a major polymorphic phase, yielding quantitative details of the spatial distribution of the two polymorphs within particles in a powder sample.

Funder

H2020 European Research Council

Centre National de la Recherche Scientifique

Cardiff University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC02063K

Reference65 articles.

1. J.Bernstein , Polymorphism in Molecular Crystals , Oxford University Press , Oxford , 2002