The influence of solvent composition on the coordination environment of the Co/Mn/Br based <i>para</i>-xylene oxidation catalyst as revealed by EPR and ESEEM spectroscopy-Reference-Cited by-同舟云学术

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The influence of solvent composition on the coordination environment of the Co/Mn/Br based para-xylene oxidation catalyst as revealed by EPR and ESEEM spectroscopy

Published:2022 Issue:17 Volume:12 Page:5274-5280
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Taylor Rebekah L.¹^ORCID,Housley Duncan²^ORCID,Barter Michael³^ORCID,Porch Adrian³^ORCID,Whiston Keith²^ORCID,Folli Andrea¹^ORCID,Murphy Damien M.¹^ORCID

Affiliation:

1. School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, CF10 3AT, UK

2. The Wilton Centre, Koch Technology Solutions Ltd., Wilton, Redcar, TS10 4RE, UK

3. School of Engineering, Cardiff University, The Parade, Cardiff CF24 3AA, UK

Abstract

The industrially important para-xylene oxidation reaction, based on a Co/Mn/Br catalyst, operates in a water/acetic acid (H2O/AcOH) solvent system.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CY/D2CY00496H

Reference24 articles.

1. Characterization of the reaction of cobalt(II) acetate, dioxygen and acetic acid, and its significance in autoxidation reactions

2. The Structure of the Homogeneous Oxidation Catalyst, Mn(II)(Br-1)x, in Supercritical Water: An X-ray Absorption Fine-Structure Study

3. Methodology and scope of metal/bromide autoxidation of hydrocarbons

4. The Complex Synergy of Water in the Metal/Bromide Autoxidation of Hydrocarbons Caused by Benzylic Bromide Formation

5. V. A.Adamian and W. H.Gong , in Liquid Phase Aerobic Oxidation Catalysis Industrial Applications and Academic Perspectives , ed. S. S. Stahl and P. L. Alsters , WILEY-VCH , 1st edn, 2016 , ch. 4, vol. 1 , pp. 41–66

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