Stereoselective construction of sterically hindered oxaspirocycles via chiral bidentate directing group-mediated C(sp3)–O bond formation
Author:
Affiliation:
1. Department of Chemistry
2. Korea Advanced Institute of Science and Technology (KAIST)
3. Daejeon
4. Korea
5. Center for Catalytic Hydrocarbon Functionalizations
Abstract
A new, bidentate, chiral directing group derived from 2,2-dimethyl-1-(pyridin-2-yl)propan-1-amine was discovered, which enables stereoselective palladium(ii)-catalyzed intramolecular C(sp3)–O bond formation.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/SC/C7SC04691J
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