Mixed-valence gold bis(diselenolene) complex turning metallic under pressure-Reference-Cited by-同舟云学术

Mixed-valence gold bis(diselenolene) complex turning metallic under pressure

Published:2021 Issue:36 Volume:9 Page:12291-12302
ISSN:2050-7526
Container-title:Journal of Materials Chemistry C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Le Gal Yann¹,Cui HengBo²,Alemany Pere³^ORCID,Canadell Enric⁴^ORCID,Kato Reizo²^ORCID,Roisnel Thierry¹^ORCID,Dorcet Vincent¹,Fourmigué Marc¹^ORCID,Lorcy Dominique¹^ORCID

Affiliation:

1. Univ. Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes) – UMR 6226, F-35000 Rennes, France

2. Condensed Molecular Materials Laboratory, RIKEN, Wako-Shi, Saitama 351-0198, Japan

3. Departament de Ciència de Materials i Química Física and Institut de Química Teòrica i Computacional (IQTCUB), Universitat de Barcelona, Martí i Franquès 1, 08028 Barcelona, Spain

4. Institut de Ciència de Materials de Barcelona, ICMAB-CSIC, Campus de la UAB, 08193 Bellaterra, Spain

Abstract

A rare mixed-valence gold bis(diselenolene) complex, exhibiting charge order between cis and trans isomers stabilized by C–H⋯S interactions, turns metallic under high pressure (>10 GPa)

Funder

Japan Society for the Promotion of Science

Ministerio de Economía y Competitividad

Generalitat de Catalunya

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/TC/D1TC02751D

Reference73 articles.

1. A Three-Dimensional Synthetic Metallic Crystal Composed of Single-Component Molecules