Molecular engineering to achieve AIE-active photosensitizers with NIR emission and rapid ROS generation efficiency

Author:

Ding Guanyu1,Tong Jialin2ORCID,Gong Jianye3,Wang Zhiming4ORCID,Su Zhongmin1ORCID,Liu Lu4,Han Xu1,Wang Jianguo3ORCID,Zhang Lingyu2ORCID,Wang Xinlong2ORCID,Wen Li-Li5,Shan Guo-Gang2ORCID

Affiliation:

1. School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun, Jilin, 130022, P. R. China

2. Institute of Functional Material Chemistry and National & Local United Engineering Lab for Power Battery, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, P. R. China

3. College of Chemistry and Chemical Engineering, Inner Mongolia Key Laboratory of Fine Organic Synthesis, Inner Mongolia University, Hohhot, 010021, P. R. China

4. State Key Laboratory of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates, Center for Aggregation-Induced Emission, Guangzhou International Campus, South China University of Technology (SCUT), Guangzhou 510640, China

5. School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun, 130022, P. R. China

Abstract

To deepen the understanding of the structure-property relationship, three AIEgens named DBP, TBP, and TBP-SO3 are designed. By controlling the ability of D–A units, TBP-SO3 realizes efficient NIR emission and a more rapid ROS generation ability.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Natural Science Foundation of Jilin Province

China Postdoctoral Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Biomedical Engineering,General Chemistry,General Medicine

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