Non-covalent interactions of the hydroperoxo group in crystalline adducts of organic hydroperoxides and their potassium salts

Author:

Buldashov Ivan A.12ORCID,Medvedev Alexander G.1ORCID,Mikhaylov Alexey A.1ORCID,Churakov Andrei V.1ORCID,Lev Ovadia3ORCID,Prikhodchenko Petr V.1ORCID

Affiliation:

1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii prosp. 31, Moscow 119991, Russia

2. Faculty of Chemistry, National Research University Higher School of Economics, Miasnitskaya Str. 20, Moscow 101000, Russia

3. The Casali Center, The Institute of Chemistry, and The Harvey M. Krueger Family Center for Nanoscience and Nanotechnology, The Hebrew University of Jerusalem, Edmond J. Safra Campus, Jerusalem 91904, Israel

Abstract

X-ray diffraction of three new stable cocrystals of potassium salts of organic hydroperoxides with molecular hydroperoxides reveals strong charge-assisted ROO⋯HOOR H-bonds.

Funder

Russian Science Foundation

Israel Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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