Electrochemical selenium-catalyzed <i>para</i>-amination of <i>N</i>-aryloxyamides: access to polysubstituted aminophenols-Reference-Cited by-同舟云学术

Electrochemical selenium-catalyzed para-amination of N-aryloxyamides: access to polysubstituted aminophenols

Published:2023 Issue:39 Volume:21 Page:7895-7899
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Gao Lei¹,Wang Zhi-Feng¹²,Wang Lin-Wei¹,Tang Hai-Tao¹^ORCID,Mo Zu-Yu¹³^ORCID,He Mu-Xue¹³^ORCID

Affiliation:

1. Guangxi Key Laboratory of Drug Discovery and Optimization, Guangxi Engineering Research Center for Pharmaceutical Molecular Screening and Druggability Evaluation, Pharmacy School of Guilin Medical University, Guilin 541199, People's Republic of China

2. Department of Burn, Wound Repair Surgery and Plastic Surgery, Department of Aesthetic Surgery, Affiliated Hospital of Guilin Medical University, Guilin 541001, People's Republic of China

3. Key Laboratory of Agricultural Resources Chemistry and Biotechnology, College of Chemistry and Food Science of Yulin Normal University, Yulin 537000, People's Republic of China

Abstract

We have developed a mild method for selenium catalyzed intramolecular rearrangement of N-aryloxyamides to produce para amination products under electrochemical conditions. The method has the advantages of high efficiency, high atom utilization and environmental friendliness.

Funder

State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources

Middle-aged and Young Teachers' Basic Ability Promotion Project of Guangxi

Natural Science Foundation of Guangxi Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/OB/D3OB01116J

Reference37 articles.

1. Recent progress in selenium-catalyzed organic reactions

2. Selenium-catalyzed Functionalization of Alkynes

3. Selenium-catalyzed oxidation of alkenes: insight into the mechanisms and developing trend

4. Regiocontrolled allylic functionalization of internal alkene via selenium-π-acid catalysis guided by boron substitution

5. Selenium-catalyzed nonradical chlorination of olefins with N-chlorosuccinimide