Atypical stoichiometry for a 3D bimetallic oxalate-based long-range ordered magnet exhibiting high proton conductivity-Reference-Cited by-同舟云学术

Atypical stoichiometry for a 3D bimetallic oxalate-based long-range ordered magnet exhibiting high proton conductivity

Published:2014 Issue:42 Volume:50 Page:5629-5632
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Maxim Catalin¹²³⁴⁵,Ferlay Sylvie¹²³⁴⁶,Tokoro Hiroko⁷⁸⁹¹⁰,Ohkoshi Shin-Ichi⁷⁸⁹¹⁰,Train Cyrille⁵¹¹¹²¹³¹¹

Affiliation:

1. Molecular Tectonic Laboratory

2. UMR UDS-CNRS 7140

3. Université de Strasbourg

4. F-67000 Strasbourg, France

5. CNRS

6. Institut Universitaire de France (IUF)

7. Department of Chemistry

8. School of Science

9. University of Tokyo

10. Tokyo 113-0033, Japan

11. LNCMI

12. F-38042 Grenoble cedex 9, France

13. University Grenoble Alpes

Abstract

A 3D achiral oxalate based coordination compound of formula (NH₄)₅[Mn^II₂Cr^III₃(ox)₉]·10H₂O, with an unusual Mn^II/Cr^IIIratio, exhibits an antiferromagnetic long-range ordering whereas its guests favour high proton conductivity.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C4CC00607K

Reference31 articles.

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5. A Concept for the Synthesis of 3-Dimensional Homo- and Bimetallic Oxalate-Bridged Networks [M2(ox)3]n. Structural, Moessbauer, and Magnetic Studies in the Field of Molecular-Based Magnets

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