A supramolecularly tunable chiral diphosphine ligand: application to Rh and Ir-catalyzed enantioselective hydrogenation-Reference-Cited by-同舟云学术

A supramolecularly tunable chiral diphosphine ligand: application to Rh and Ir-catalyzed enantioselective hydrogenation

Published:2016 Issue:7 Volume:7 Page:4594-4599
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Zhang Xi-Chang¹²³⁴⁵,Hu Yi-Hu¹²³⁴,Chen Chuan-Fu¹²³⁴,Fang Qiang¹²³⁴,Yang Li-Yao¹²³⁴,Lu Ying-Bo¹²³⁴,Xie Lin-Jie¹²³⁴,Wu Jing¹²³⁴,Li Shijun¹²³⁴,Fang Wenjun⁵⁶³⁴

Affiliation:

1. College of Material, Chemistry and Chemical Engineering

2. Hangzhou Normal University

3. Hangzhou

4. China

5. Department of Chemistry

6. Zhejiang University

Abstract

A supramolecularly tunable chiral bisphosphine ligand bearing two pyridyl-containing crown ethers was synthesized and applied in Rh or Ir-catalyzed asymmetric hydrogenations in high yields with excellent ee values (90–99% ee).

Funder

National Natural Science Foundation of China

Natural Science Foundation of Zhejiang Province

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C6SC00589F

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