Thermal catalytic mineralization of ortho-dichlorobenzene at low temperature: an in situ FT-IR and XPS mechanistic investigation

Author:

Kumar Adarsh12,Tyagi Deepak12,Varma Salil12,Chand Hushan3,Krishnan V.3ORCID,Bhattacharyya K.12ORCID,Tyagi A. K.12ORCID

Affiliation:

1. Chemistry Division, Bhabha Atomic Research Centre, Mumbai-400 085, India

2. Homi Bhabha National Institute, Mumbai – 400 094, India

3. Indian Institute of Technology- Mandi, Kamand, Mandi – 175 075, India

Abstract

The VWC-catalyst thermally mineralizes o-DCB [a surrogate moiety representing dioxin and furan] at 120 °C for the first time in oxidative and non-oxidative condition with strong effect of lattice oxygen establishing its reaction mechanism.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Chemistry (miscellaneous)

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