[Ag(bpy)(PPhtBu2)(OCF3)]: a stable nucleophilic reagent for chemoselective and stereospecific trifluoromethoxylation of secondary alkyl nosylates-Reference-Cited by-同舟云学术

[Ag(bpy)(PPhtBu2)(OCF3)]: a stable nucleophilic reagent for chemoselective and stereospecific trifluoromethoxylation of secondary alkyl nosylates

Published:2019 Issue:11 Volume:6 Page:1801-1806
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Chen Daoqian¹²³⁴⁵,Lu Long³⁶⁷,Shen Qilong¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Organofluorine Chemistry

2. Center for Excellence in Molecular Synthesis

3. Shanghai Institute of Organic Chemistry

4. University of Chinese Academy of Sciences

5. Chinese Academy of Sciences

6. Shanghai 200032

7. China

Abstract

The development of a thermally stable and light-insensitive nucleophilic trifluoromethoxylative reagent [Ag(bpy)(PPh^tBu₂)(OCF₃)] 2, which was synthesized in high yields via a three-step one-pot process from easily available trifluoromethyl triflate (TFMT) and AgF at room temperature, is described.

Funder

National Natural Science Foundation of China

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/QO/C9QO00278B

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