Thiophene- and bithiophene-based π-conjugated Schiff base oligomers containing binaphthalene moieties in the backbone. Properties and computational simulations

Author:

González Alexis F.1,Mariman Andrea P.1,Hauyon René A.1,Pavez-Lizana Danitza1,Saldías César2,Schott Eduardo3,Zarate Ximena4,Garcia Luis1,González-Henríquez Carmen M.5,Jessop Ignacio A.6,Tundidor-Camba Alain1ORCID,Sobarzo Patricio A.1,Terraza Claudio A.1ORCID

Affiliation:

1. Research Laboratory for Organic Polymers (RLOP), Faculty of Chemistry and of Pharmacy, Pontificia Universidad Católica de Chile, Santiago, Chile

2. Department of Physical Chemistry, Pontificia Universidad Católica de Chile, Santiago, Chile

3. Department of Inorganic Chemistry, Pontificia Universidad Católica de Chile, Santiago, Chile

4. Institute of Applied Chemical Sciences, Faculty of Engineering, Universidad Autónoma de Chile, Santiago, Chile

5. Laboratory of Nanotechnology and Advanced Materials, Department of Chemistry, Universidad Tecnológica Metropolitana, Santiago, Chile

6. Organic and Polymeric Materials Research Laboratory, Department of Chemistry, Universidad de Tarapacá, Arica, Chile

Abstract

Schiff base oligomers based on a binaphthalene core were synthesized from [1,1′-binaphthalene]-4,4′-diamine with thiophene-2,5-dicarbaldehyde and [2,2′-bithiophene]-5,5′-dicarbaldehyde by a high-temperature polycondensation method.

Funder

Fondo Nacional de Desarrollo Científico y Tecnológico

Publisher

Royal Society of Chemistry (RSC)

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