An anthraquinone-based bismuth–iron metal–organic framework as an efficient photoanode in photoelectrochemical cells

Author:

Shi Cai1,Gomez-Mendoza Miguel2,Gómez de Oliveira Eloy1,García-Tecedor Miguel2ORCID,Barawi Mariam2ORCID,Esteban-Betegón Fátima1,Liras Marta2ORCID,Gutiérrez-Puebla Enrique1ORCID,Monge Angeles1ORCID,de la Peña O'Shea Víctor A.2ORCID,Gándara Felipe1ORCID

Affiliation:

1. Materials Science Institute of Madrid – Spanish National Research Council, Sor Juana Inés de la Cruz, 3, 28049, Madrid, Spain

2. Photoactivated Processes Unit, IMDEA Energy Institute, Móstoles Technology Park, Avenida Ramón de la Sagra 3, Móstoles, 28935, Madrid, Spain

Abstract

A new metal–organic framework formed by iron and bismuth, and an anthraquinone linker is demonstrated to be an efficient photoanode in photoelectrochemical cells. An intermediate anion radical is generated under visible light, with a long lifetime.

Funder

Ministerio de Ciencia, Innovación y Universidades

'la Caixa' Foundation

Publisher

Royal Society of Chemistry (RSC)

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