DFT exchange: sharing perspectives on the workhorse of quantum chemistry and materials science

Author:

Teale Andrew M.1ORCID,Helgaker Trygve2ORCID,Savin Andreas3ORCID,Adamo Carlo4ORCID,Aradi Bálint5ORCID,Arbuznikov Alexei V.6ORCID,Ayers Paul W.7ORCID,Baerends Evert Jan8ORCID,Barone Vincenzo9ORCID,Calaminici Patrizia10ORCID,Cancès Eric11ORCID,Carter Emily A.12ORCID,Chattaraj Pratim Kumar13ORCID,Chermette Henry14ORCID,Ciofini Ilaria4ORCID,Crawford T. Daniel1516ORCID,De Proft Frank17ORCID,Dobson John F.18ORCID,Draxl Claudia1920ORCID,Frauenheim Thomas52122,Fromager Emmanuel23ORCID,Fuentealba Patricio24ORCID,Gagliardi Laura25ORCID,Galli Giulia26ORCID,Gao Jiali2728ORCID,Geerlings Paul17ORCID,Gidopoulos Nikitas29ORCID,Gill Peter M. W.30ORCID,Gori-Giorgi Paola31ORCID,Görling Andreas32ORCID,Gould Tim33ORCID,Grimme Stefan34ORCID,Gritsenko Oleg31ORCID,Jensen Hans Jørgen Aagaard35ORCID,Johnson Erin R.36ORCID,Jones Robert O.37ORCID,Kaupp Martin6ORCID,Köster Andreas M.10ORCID,Kronik Leeor38ORCID,Krylov Anna I.39ORCID,Kvaal Simen2ORCID,Laestadius Andre2ORCID,Levy Mel40ORCID,Lewin Mathieu41ORCID,Liu Shubin4243ORCID,Loos Pierre-François44ORCID,Maitra Neepa T.45ORCID,Neese Frank46ORCID,Perdew John P.47ORCID,Pernal Katarzyna48ORCID,Pernot Pascal49ORCID,Piecuch Piotr5051ORCID,Rebolini Elisa52ORCID,Reining Lucia5354ORCID,Romaniello Pina55ORCID,Ruzsinszky Adrienn56ORCID,Salahub Dennis R.57ORCID,Scheffler Matthias58ORCID,Schwerdtfeger Peter59ORCID,Staroverov Viktor N.60ORCID,Sun Jianwei61ORCID,Tellgren Erik2ORCID,Tozer David J.62ORCID,Trickey Samuel B.63ORCID,Ullrich Carsten A.64ORCID,Vela Alberto10ORCID,Vignale Giovanni65ORCID,Wesolowski Tomasz A.66ORCID,Xu Xin67ORCID,Yang Weitao68ORCID

Affiliation:

1. School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, UK

2. Hylleraas Centre for Quantum Molecular Sciences, Department of Chemistry, University of Oslo, P.O. Box 1033 Blindern, N-0315 Oslo, Norway

3. Laboratoire de Chimie Théorique, CNRS and Sorbonne University, 4 Place Jussieu, CEDEX 05, 75252 Paris, France

4. PSL University, CNRS, ChimieParisTech-PSL, Institute of Chemistry for Health and Life Sciences, i-CLeHS, 11 rue P. et M. Curie, 75005 Paris, France

5. Bremen Center for Computational Materials Science, University of Bremen, P.O. Box 330440, D-28334 Bremen, Germany

6. Technische Universität Berlin, Institut für Chemie, Theoretische Chemie/Quantenchemie, Sekr. C7, Straße des 17. Juni 135, 10623, Berlin

7. McMaster University, Hamilton, Ontario, Canada

8. Department of Chemistry and Pharmaceutical Sciences, Faculty of Science, Vrije Universiteit, De Boelelaan 1083, 1081HV Amsterdam, The Netherlands

9. Scuola Normale Superiore, Piazza dei Cavalieri 7, 56125 Pisa, Italy

10. Departamento de Química, Centro de Investigación y de Estudios Avanzados (Cinvestav), CDMX, 07360, Mexico

11. CERMICS, Ecole des Ponts and Inria Paris, 6 Avenue Blaise Pascal, 77455 Marne-la-Vallée, France

12. Department of Mechanical and Aerospace Engineering and the Andlinger Center for Energy and the Environment, Princeton University, Princeton, NJ 08544-5263, USA

13. Department of Chemistry, Indian Institute of Technology, Kharagpur, 721302, India

14. Institut Sciences Analytiques, Université Claude Bernard Lyon1, CNRS UMR 5280, 69622 Villeurbanne, France

15. Department of Chemistry, Virginia Tech, Blacksburg, VA 24061, USA

16. Molecular Sciences Software Institute, Blacksburg, VA 24060, USA

17. Research Group of General Chemistry (ALGC), Vrije Universiteit Brussel (VUB), Pleinlaan 2, B-1050 Brussels, Belgium

18. Griffith University, Nathan, Queensland 4111, Australia

19. Institut für Physik and IRIS Adlershof, Humboldt-Universität zu Berlin, 12489 Berlin, Germany

20. Fritz-Haber-Institut der Max-Planck-Gesellschaft, 14195 Berlin, Germany

21. Beijing Computational Science Research Center (CSRC), 100193 Beijing, China

22. Shenzhen JL Computational Science and Applied Research Institute, 518110 Shenzhen, China

23. Laboratoire de Chimie Quantique, Institut de Chimie, CNRS/Université de Strasbourg, 4 rue Blaise Pascal, 67000 Strasbourg, France

24. Departamento de Física, Facultad de Ciencias, Universidad de Chile, Casilla 653, Santiago, Chile

25. Department of Chemistry, Pritzker School of Molecular Engineering, The James Franck Institute, and Chicago Center for Theoretical Chemistry, The University of Chicago, Chicago, Illinois 60637, USA

26. Pritzker School of Molecular Engineering and Department of Chemistry, The University of Chicago, Chicago, IL, USA

27. Institute of Systems and Physical Biology, Shenzhen Bay Laboratory, Shenzhen 518055, China

28. Department of Chemistry, University of Minnesota, Minneapolis, MN 55455, USA

29. Department of Physics, Durham University, South Road, Durham DH1 3LE, UK

30. School of Chemistry, University of Sydney, Camperdown NSW 2006, Australia

31. Department of Chemistry and Pharmaceutical Sciences, Amsterdam Institute of Molecular and Life Sciences (AIMMS), Faculty of Science, Vrije Universiteit, De Boelelaan 1083, 1081HV Amsterdam, The Netherlands

32. Chair of Theoretical Chemistry, University of Erlangen-Nuremberg, Egerlandstrasse 3, 91058 Erlangen, Germany

33. Qld Micro- and Nanotechnology Centre, Griffith University, Gold Coast, Qld 4222, Australia

34. Mulliken Center for Theoretical Chemistry, University of Bonn, Beringstrasse 4, 53115 Bonn, Germany

35. Department of Physics, Chemistry and Pharmacy, University of Southern Denmark, DK-5230 Odense M, Denmark

36. Department of Chemistry, Dalhousie University, Halifax, Nova Scotia, B3H 4R2, Canada

37. Peter Grünberg Institut PGI-1, Forschungszentrum Jülich, 52425 Jülich, Germany

38. Department of Molecular Chemistry and Materials Science, Weizmann Institute of Science, Rehovoth, 76100, Israel

39. Department of Chemistry, University of Southern California, Los Angeles, California 90089, USA

40. Department of Chemistry, Tulane University, New Orleans, Louisiana, 70118, USA

41. CNRS & CEREMADE, Université Paris-Dauphine, PSL Research University, Place de Lattre de Tassigny, 75016 Paris, France

42. Research Computing Center, University of North Carolina, Chapel Hill, NC 27599-3420, USA

43. Department of Chemistry, University of North Carolina, Chapel Hill, NC 27599-3290, USA

44. Laboratoire de Chimie et Physique Quantiques (UMR 5626), Université de Toulouse, CNRS, UPS, France

45. Department of Physics, Rutgers University at Newark, 101 Warren Street, Newark, NJ 07102, USA

46. Max Planck Institut für Kohlenforschung, Kaiser Wilhelm Platz 1, D-45470 Mülheim an der Ruhr, Germany

47. Departments of Physics and Chemistry, Temple University, Philadelphia, PA 19122, USA

48. Institute of Physics, Lodz University of Technology, ul. Wolczanska 219, 90-924 Lodz, Poland

49. Institut de Chimie Physique, UMR8000, CNRS and Université Paris-Saclay, Bât. 349, Campus d’Orsay, 91405 Orsay, France

50. Department of Chemistry, Michigan State University, East Lansing, Michigan 48824, USA

51. Department of Physics and Astronomy, Michigan State University, East Lansing, Michigan 48824, USA

52. Institut Laue Langevin, 71 avenue des Martyrs, 38000 Grenoble, France

53. Laboratoire des Solides Irradiés, CNRS, CEA/DRF/IRAMIS, École Polytechnique, Institut Polytechnique de Paris, F-91120 Palaiseau, France

54. European Theoretical Spectroscopy Facility,

55. Laboratoire de Physique Théorique (UMR 5152), Université de Toulouse, CNRS, UPS, France

56. Department of Physics, Temple University, Philadelphia, Pennsylvania 19122, USA

57. Department of Chemistry, Department of Physics and Astronomy, CMS – Centre for Molecular Simulation, IQST – Institute for Quantum Science and Technology, Quantum Alberta, University of Calgary, 2500 University Drive NW, Calgary, Alberta, T2N 1N4, Canada

58. The NOMAD Laboratory at the FHI of the Max-Planck-Gesellschaft and IRIS-Adlershof of the Humboldt-Universität zu Berlin, Faradayweg 4-6, D-14195, Germany

59. Centre for Theoretical Chemistry and Physics, The New Zealand Institute for Advanced Study, Massey University Auckland, 0632 Auckland, New Zealand

60. Department of Chemistry, The University of Western Ontario, London, Ontario N6A 5B7, Canada

61. Department of Physics and Engineering Physics, Tulane University, New Orleans, LA 70118, USA

62. Department of Chemistry, Durham University, South Road, Durham, DH1 3LE, UK

63. Quantum Theory Project, Deptartment of Physics, University of Florida, Gainesville, FL 32611, USA

64. Department of Physics and Astronomy, University of Missouri, Columbia, MO 65211, USA

65. Department of Physics, University of Missouri, Columbia, MO 65203, USA

66. Department of Physical Chemistry, Université de Genève, 30 Quai Ernest-Ansermet, 1211 Genève, Switzerland

67. Shanghai Key Laboratory of Molecular Catalysis and Innovation Materials, Collaborative Innovation Centre of Chemistry for Energy Materials, MOE Laboratory for Computational Physical Science, Department of Chemistry, Fudan University, Shanghai 200433, China

68. Department of Chemistry and Physics, Duke University, Durham, NC 27516, USA

Abstract

In this paper, the history, present status, and future of density-functional theory (DFT) is informally reviewed and discussed by 70 workers in the field, including molecular scientists, materials scientists, method developers and practitioners.

Funder

LabEx Chimie des Systèmes Complexes

Australian Research Council

U.S. Department of Energy

National Natural Science Foundation of China

Julian Schwinger Foundation for Physics Research

H2020 European Research Council

National Science Foundation

Norges Forskningsråd

Deutsche Forschungsgemeinschaft

Horizon 2020 Framework Programme

Agence Nationale de la Recherche

Natural Sciences and Engineering Research Council of Canada

Vrije Universiteit Brussel

National Institutes of Health

Leverhulme Trust

Department of Science and Technology, Ministry of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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