Synthesis of phosphiranes <i>via</i> organoiron-catalyzed phosphinidene transfer to electron-deficient olefins-Reference-Cited by-同舟云学术

Synthesis of phosphiranes via organoiron-catalyzed phosphinidene transfer to electron-deficient olefins

Published:2022 Issue:43 Volume:13 Page:12696-12702
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Xin Tiansi¹^ORCID,Geeson Michael B.¹^ORCID,Zhu Hui²,Qu Zheng-Wang²^ORCID,Grimme Stefan²^ORCID,Cummins Christopher C.¹^ORCID

Affiliation:

1. Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, USA

2. Mulliken Center for Theoretical Chemistry, University of Bonn, Beringstr. 4, 53115 Bonn, Germany

Abstract

The iconic cyclopentadienyliron dicarbonyl dimer ([CpFe(CO)2]2 or Fp2) catalyzes phosphinidene group transfer from anthracene to activated alkenes, forming new phosphiranes diastereoselectively and with good isolated yields.

Funder

Deutsche Forschungsgemeinschaft

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC05011K

Reference55 articles.

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2. D. S.Glueck , in Comprehensive Heterocyclic Chemistry IV , ed. D. S. Black , J. Cossy and C. V. Stevens , Elsevier , Oxford , 2022 , pp. 464–505

3. Synthesis and Reactivity of Phosphirane Ligands and the Structural Characterization of Cp*IrCl2(tert-butylphosphirane)

4. Synthesis of 1-(9-Anthracene)phosphirane and Novel Intramolecular π-Stacking of 1-(9-Anthracene)phosphirane Ligands in a cis-Platinum(II) Complex

5. Phosphiranes as Ligands for Platinum Catalysed Hydrosilylations

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