Metal–ligand cooperative activation of nitriles by a ruthenium complex with a de-aromatized PNN pincer ligand-Reference-Cited by-同舟云学术

Metal–ligand cooperative activation of nitriles by a ruthenium complex with a de-aromatized PNN pincer ligand

Published:2016 Issue:40 Volume:45 Page:16033-16039
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Eijsink Linda E.¹²³⁴,Perdriau Sébastien C. P.¹²³⁴,de Vries Johannes G.¹²³⁴⁵,Otten Edwin¹²³⁴

Affiliation:

1. Stratingh Institute for Chemistry

2. University of Groningen

3. 9747 AG Groningen

4. The Netherlands

5. Leibniz-Institut für Katalyse an der Universität Rostock

Abstract

Metal–ligand cooperative activation of nitriles by a de-aromatized Ru pincer complex leads to equilibrium mixtures (tautomers) as a result of ligand deprotonation by the Brønsted basic Ru-ketimido moiety.

Funder

Nederlandse Organisatie voor Wetenschappelijk Onderzoek

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT02478E

Reference33 articles.

1. G. Van Koten and D.Milstein, Organometallic Pincer Chemistry, Springer, Berlin Heidelberg, 2013

2. Metal–Ligand Cooperation by Aromatization–Dearomatization: A New Paradigm in Bond Activation and “Green” Catalysis

3. Multidentate actor ligands as versatile platforms for small molecule activation and catalysis

4. Bond Activation and Catalysis by Ruthenium Pincer Complexes

5. Metal-Ligand Cooperation

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