Metal–ligand cooperative activation of nitriles by a ruthenium complex with a de-aromatized PNN pincer ligand
Author:
Affiliation:
1. Stratingh Institute for Chemistry
2. University of Groningen
3. 9747 AG Groningen
4. The Netherlands
5. Leibniz-Institut für Katalyse an der Universität Rostock
Abstract
Metal–ligand cooperative activation of nitriles by a de-aromatized Ru pincer complex leads to equilibrium mixtures (tautomers) as a result of ligand deprotonation by the Brønsted basic Ru-ketimido moiety.
Funder
Nederlandse Organisatie voor Wetenschappelijk Onderzoek
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT02478E
Reference33 articles.
1. G. Van Koten and D.Milstein, Organometallic Pincer Chemistry, Springer, Berlin Heidelberg, 2013
2. Metal–Ligand Cooperation by Aromatization–Dearomatization: A New Paradigm in Bond Activation and “Green” Catalysis
3. Multidentate actor ligands as versatile platforms for small molecule activation and catalysis
4. Bond Activation and Catalysis by Ruthenium Pincer Complexes
5. Metal-Ligand Cooperation
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