Metal-free cascade reactions for one-pot tetrahydroquinoxaline construction through nitroarene reduction and imine hydrogenation with water-Reference-Cited by-同舟云学术

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Metal-free cascade reactions for one-pot tetrahydroquinoxaline construction through nitroarene reduction and imine hydrogenation with water

Published:2024 Issue:14 Volume:48 Page:6103-6108
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Chen Yanqi¹,Hao Subin¹,Yin Lingfeng¹,Song Xinluo¹,Liu Zhiyao¹,Li Mingde¹^ORCID,Dang Li¹^ORCID

Affiliation:

1. Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Guangdong 515063, P. R. China

Abstract

A metal-free one-pot cascade process of imines with B2cat2 and water has been developed to construct dihydroquinoxalinones and tetrahydroquinoxalines directly from readily available 2-nitroanilines or o-dinitrobenzenes with α-ketoesters and α-diketones.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/NJ/D3NJ05093A

Reference31 articles.

1. Versatile (Pentamethylcyclopentadienyl)rhodium-2,2′-Bipyridine (Cp*Rh-bpy) Catalyst for Transfer Hydrogenation of N-Heterocycles in Water

2. Nickel-catalyzed borrowing hydrogen annulations: access to diversified N-heterocycles

3. Borane‐Catalyzed Tandem Cyclization/Hydrosilylation Towards Enantio‐ and Diastereoselective Construction of trans‐2,3‐Disubstituted‐1,2,3,4‐Tetrahydroquinoxalines

4. Metal-Free Deoxygenation and Reductive Disilylation of Nitroarenes by Organosilicon Reducing Reagents

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