Organometallic molecular wires as versatile modules for energy-level alignment of the metal–molecule

Organometallic molecular wires as versatile modules for energy-level alignment of the metal–molecule–metal junction

Published:2016 Issue:34 Volume:52 Page:5796-5799
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Sugimoto Kaho¹²³⁴,Tanaka Yuya¹²³⁴,Fujii Shintaro⁵⁶²⁷⁴,Tada Tomofumi⁸²⁹⁴,Kiguchi Manabu⁵⁶²⁷⁴,Akita Munetaka¹²³⁴

Affiliation:

1. Chemical Resources Laboratory

2. Tokyo Institute of Technology

3. Yokohama 226-8503

4. Japan

5. Department of Chemistry

6. Graduate School of Science and Engineering

7. Tokyo 152-8551

8. Materials Research Center for Element Strategy

9. Yokohama

Abstract

Organometallic Ru molecular wires show significantly higher conductance compared to their organic counterpart due to high-lying HOMOs.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC01705C

Reference32 articles.

1. Electronics using hybrid-molecular and mono-molecular devices

2. Electron Transport in Molecular Wire Junctions

3. Ab Initio Investigations of the Electric Field Dependence of the Geometric and Electronic Structures of Molecular Wires

4. Single-Molecule Conductance of Functionalized Oligoynes: Length Dependence and Junction Evolution

5. Length‐Dependent Conductance of Molecular Wires and Contact Resistance in Metal–Molecule–Metal Junctions

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