Synthesis of ene-yne-enes by nickel-catalyzed double SN2′ substitution of 1,6-dichlorohexa-2,4-diyne
Author:
Affiliation:
1. Stratingh Institute for Chemistry
2. University of Groningen
3. Groningen
4. The Netherlands
Abstract
1,6-Dichlorohexa-2,4-diyne undergoes nickel-catalyzed double substitution with aryl and alkenyl Grignard reagents to provide substituted ene-yne-enes.
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2017/CY/C7CY00429J
Reference54 articles.
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2. A. Alexakis , N.Krause and S.Woodward in Copper-Catalyzed Asymmetric Synthesis, ed. A. Alexakis, N. Krause and S. Woodward, Wiley-VCH, Weinheim, 1st edn, 2014, p. 33
3. Copper-Catalyzed Propargylic Substitution of Dichloro Substrates: Enantioselective Synthesis of Trisubstituted Allenes and Formation of Propargylic Quaternary Stereogenic Centers
4. Small but Effective: Copper Hydride Catalyzed Synthesis of α-Hydroxyallenes
5. (NHC)CuH-Catalyzed Entry to Allenes via Propargylic Carbonate SN2′-Reductions
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