Synthesis of chiral-at-metal rhodium complexes from achiral tripodal tetradentate ligands: resolution and application to enantioselective Diels–Alder and 1,3-dipolar cycloadditions

Author:

Tejero Alvaro G.1,Carmona María1,Rodríguez Ricardo1ORCID,Viguri Fernando1,Lahoz Fernando J.1ORCID,García-Orduña Pilar1ORCID,Carmona Daniel1ORCID

Affiliation:

1. Departamento de Catálisis y Procesos Catalíticos, Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), CSIC – Universidad de Zaragoza, Pedro Cerbuna 12, 50009 Zaragoza, Spain

Abstract

A resolved chiral-at-rhodium complex catalyses asymmetric Diels–Alder and 1,3-dipolar cycloaddition reactions with enantioselectivity of up to >99/1 er.

Funder

Agencia Estatal de Investigación

Gobierno de Aragón

Ministerio de Ciencia, Innovación y Universidades

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference46 articles.

1. Comprehensive Asymmetric Catalysis , ed. E. N. Jacobsen , A. Pfaltz and H. Yamamoto , Springer , New York , 1999 , vol. I–III

2. Catalytic Asymmetric Synthesis , ed. I. Ojima , VCH , Weinheim , 2000

3. R.Noyori , Asymmetric Catalysis in Organic Synthesis , John Willey and Sons , New York , 1994

4. P. J.Walsh and M. C.Kozlowski , Fundamentals of Asymmetric Catalysis , University Science Books , Sausalito , 2009

5. Optical induction in organo-transition-metal compounds and asymmetric catalysis

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