Synthesis and characterisation of fifteen-electron dihalo(carbonyl)tungsten(iii) complexes, Tp*WX2(CO) (X = Br, I)-Reference-Cited by-同舟云学术

Synthesis and characterisation of fifteen-electron dihalo(carbonyl)tungsten(iii) complexes, Tp*WX2(CO) (X = Br, I)

Published:2020 Issue:71 Volume:56 Page:10349-10352
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Thomas Simon¹²³,Gable Robert W.¹²³^ORCID,Young Charles G.⁴⁵⁶⁷³^ORCID

Affiliation:

1. School of Chemistry

2. University of Melbourne

3. Australia

4. Department of Chemistry and Physics

5. La Trobe Institute for Molecular Science

6. La Trobe University

7. Melbourne 3086

Abstract

Open-shell, 15-electron, d³ dihalo(carbonyl)–W^III complexes, Tp*WX₂(CO), are reported. These mononuclear, distorted octahedral complexes exhibit single ν(CO) IR bands and magnetic moments and isotropically shifted NMR spectra consistent with low-spin, double ground states.

Funder

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/D0CC04607H

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