The influence of thiocarbonylthio compounds on the B(C6F5)3 catalyzed cationic polymerization of styrene

Author:

Destephen Aurélie1,González de San Román Estibaliz1,Ballard Nicholas12ORCID

Affiliation:

1. POLYMAT, University of the Basque Country UPV/EHU, Joxe Mari Korta Center, Avenida Tolosa 72, 20018 Donostia-San Sebastián, Spain

2. Ikerbasque, Basque Foundation for Science, Plaza Euskadi 5, 48009 Bilbao, Spain

Abstract

When applied to the cationic polymerization of styrene, thiocarbonylthio compounds can lead to a dual control mechanism, where degenerative chain transfer occurs concurrent with a reversible addition mechanism.

Funder

Eusko Jaurlaritza

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Reference78 articles.

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5. Controlled and living polymerizations: from mechanisms to applications , ed. A. H. E. Müller and K. Matyjaszewski , Wiley- VCH , Weinheim, Germany , 2009

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