Bonding between electron-deficient atoms: strong Lewis-acid character preserved in X–Y–X (X = B, Al; Y = Be, Mg) bridges-Reference-Cited by-同舟云学术

Bonding between electron-deficient atoms: strong Lewis-acid character preserved in X–Y–X (X = B, Al; Y = Be, Mg) bridges

Published:2020 Issue:27 Volume:44 Page:11870-11878
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Ferrer Maxime¹²³⁴⁵,Montero-Campillo M. Merced¹²³⁴⁵^ORCID,Mó Otilia¹²³⁴⁵^ORCID,Yáñez Manuel¹²³⁴⁵^ORCID,Alkorta Ibon⁶⁷⁵^ORCID,Elguero José⁶⁷⁵^ORCID

Affiliation:

1. Departamento de Química

2. Facultad de Ciencias

3. Módulo 13, and Institute of Advanced Chemical Sciences (IadChem). Universidad Autónoma de Madrid

4. E-28049 Madrid

5. Spain

6. Instituto de Química Médica (CSIC)

7. E-28006 Madrid

Abstract

Beryllium bis(diazaborolyl) derivatives and their Mg and Al-containing analogues are stable compounds stabilized through covalent bonds between electron-deficient atoms, and behave as good Lewis acids.

Funder

Ministerio de Ciencia, Innovación y Universidades

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/NJ/D0NJ01803A

Reference47 articles.

1. Beryllium Bonds, Do They Exist?

2. The beryllium bond

3. On the existence of intramolecular one-electron Be–Be bonds

4. Beryllium-Based Anion Sponges: Close Relatives of Proton Sponges

5. Boration of an α,β-enone using a diboron promoted by a copper(I)–phosphine mixture catalyst

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1. Identification of Global Minimum of HNBeCO Complex;The Journal of Physical Chemistry A;2023-11-08

2. Clustering of Electron Deficient B‐ and Be‐Containing Analogues: In the Fight for Tetracoordination, Beryllium Takes the Lead;European Journal of Inorganic Chemistry;2021-10-11