A platform for accelerated continuous-flow radical polymerization of acrylates and styrene with copper-wire threads
Author:
Affiliation:
1. Center for Intelligent Microprocess of Pharmaceutical Synthesis
2. Department of Chemical Engineering
3. Pohang University of Science and Technology
4. Pohang
5. Republic of Korea
6. Center for Smart Block Copolymers
Abstract
Accelerated Cu(0)-mediated homo-/block (co)polymerization of the vinyl monomers is conducted via continuous-flow process with a copper metal-wire catalyst threaded through perfluoroalkoxy alkane (PFA) tube.
Funder
National Research Foundation of Korea
Publisher
Royal Society of Chemistry (RSC)
Subject
Fluid Flow and Transfer Processes,Process Chemistry and Technology,Chemical Engineering (miscellaneous),Chemistry (miscellaneous),Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2019/RE/C9RE00186G
Reference31 articles.
1. Cu(0)-Mediated Living Radical Polymerization: A Versatile Tool for Materials Synthesis
2. Ultrafast Synthesis of Ultrahigh Molar Mass Polymers by Metal-Catalyzed Living Radical Polymerization of Acrylates, Methacrylates, and Vinyl Chloride Mediated by SET at 25 °C
3. Single-Electron Transfer and Single-Electron Transfer Degenerative Chain Transfer Living Radical Polymerization
4. ATRP of Methacrylates Utilizing CuIIX2/L and Copper Wire
5. Copper-Mediated Living Radical Polymerization (Atom Transfer Radical Polymerization and Copper(0) Mediated Polymerization): From Fundamentals to Bioapplications
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1. Enhancing the Scalability of Crystallization-Driven Self-Assembly Using Flow Reactors;ACS Macro Letters;2023-11-16
2. An universal approach of catalyst immobilization inside hydrophobic PFA tubing under well dispersed manner for continuous-flow applications;Chemical Engineering Journal;2023-01
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