Total CCl4 guest alignment in a quasiracemic clathrate closely related to Dianin's compound-Reference-Cited by-同舟云学术

Total CCl4 guest alignment in a quasiracemic clathrate closely related to Dianin's compound

Published:2017 Issue:38 Volume:19 Page:5703-5706
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Frampton Christopher S.¹²³⁴^ORCID,Gall James H.⁵⁶⁷⁴,MacNicol David D.⁵⁶⁷⁴

Affiliation:

1. Wolfson Centre for Materials Processing

2. Brunel University

3. Uxbridge

4. UK

5. Department of Chemistry

6. University of Glasgow

7. Glasgow G12 8QQ

Abstract

In the trigonal CCl₄quasiracemic clathrate, space group R3, formed from host components S-(−)-Dianin's compound, 4, and its (+)-2R,4R 2-nor methyl analogue, 2, the unprecedented complete ordering of a C–Cl bond of the guest with respect to the c-axial direction and the participation of an unexpected host conformation is reported for the first time.

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CE/C7CE01275F

Reference17 articles.

1. See, for example, P.Finocchiaro and S.Failla, Other Potentially Important Hosts, in Comprehensive Supramolecular Chemistry, ed. D. D. MacNicol, F. Toda and R. Bishop, Elsevier Science, Oxford, 1996, ch. 18, vol. 6, pp. 618–632

2. R. Bishop , Synthetic Clathrate Systems, in Supramolecular Chemistry: From Molecules to Nanomaterials, ed. P. A. Gale and J. W. Steed, John Wiley & Sons, Ltd., 2012, pp. 3033–3056

3. Quantifying Host–Guest Interaction Energies in Clathrates of Dianin’s Compound

4. Molecular Imprisonment: Host Response to Guest Location, Orientation, and Dynamics in Clathrates of Dianin’s Compound

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. The first spontaneous resolution of a sulfoxide: Dianin's compound analogue, (R)-4-(4-hydroxyphenyl)-2,2,4-trimethylthiachroman-1-oxide;Acta Crystallographica Section E Crystallographic Communications;2018-10-19

2. 4-(4-Hydroxyphenyl)-2,2,4-trimethyl-7,8-benzothiachroman, a fused-ring counterpart ofthia-Dianin's compound;Acta Crystallographica Section E Crystallographic Communications;2017-10-20