Structural and conformational analysis of a biaryl phosphine integrating a calix[4]arene cavity. Can the phosphorus atom behave as an introverted donor?-Reference-Cited by-同舟云学术

Structural and conformational analysis of a biaryl phosphine integrating a calix[4]arene cavity. Can the phosphorus atom behave as an introverted donor?

Published:2023 Issue:27 Volume:52 Page:9202-9207
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Gourlaouen Christophe¹^ORCID,Elaieb Fethi²,Brenner Eric²^ORCID,Matt Dominique²^ORCID,Harrowfield Jack³^ORCID,Ricard Louis⁴

Affiliation:

1. Laboratoire de Chimie Quantique, Institut de Chimie, UMR 7177 CNRS-Université de Strasbourg, 4 rue Blaise Pascal, 67070 Strasbourg Cedex, France

2. Institut de Chimie, UMR 7177 CNRS, Université de Strasbourg, 4 Rue Blaise Pascal, 67070 Strasbourg Cedex, France

3. Institut de Science et Ingénierie Supramoléculaire (ISIS), UMR 7606 CNRS, Université de Strasbourg, 8 rue Gaspard Monge, 67083 Strasbourg Cedex, France

4. Laboratoire de Chimie Moléculaire, CNRS UMR 9168, Ecole Polytechnique, 2 route de Saclay, F-91128 Palaiseau Cedex, France

Abstract

Conformational analysis of a calix[4]arene-based biaryl phosphine revealed how the presence of the cavity-shaped calixarene core may profoundly alter the steric properties of the ligand.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT00612C

Reference41 articles.

1. Phosphines and other P(III)‐derivatives with Cavity‐shaped Subunits: Valuable Ligands for Supramolecular Metal Catalysis, Metal Confinement and Subtle Steric Control

2. Synthetic Application of Cyclodextrins in Combination with Metal Ions, Complexes, and Metal Particles

3. Merging Molecular Recognition and Gold(I) Catalysis with Triphoscalix[6]arene Ligands

4. Cavity-shaped ligands for asymmetric metal catalysis

5. Synthesis of tetra-pincer nickel(ii) and palladium(ii) complexes of resorcin[4]arene-octophosphinite [Res(OPR2)8] and rhodium-catalyzed regioselective hydroformylation reaction