Ligand design for Rh(iii)-catalyzed C–H activation: an unsymmetrical cyclopentadienyl group enables a regioselective synthesis of dihydroisoquinolones-Reference-Cited by-同舟云学术

Ligand design for Rh(iii)-catalyzed C–H activation: an unsymmetrical cyclopentadienyl group enables a regioselective synthesis of dihydroisoquinolones

Published:2015 Issue:1 Volume:6 Page:254-258
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Hyster Todd K.¹²³⁴,Dalton Derek M.¹²³⁴,Rovis Tomislav¹²³⁴

Affiliation:

1. Department of Chemistry

2. Colorado State University

3. Fort Collins

4. USA

Abstract

A modified cyclopentadienyl ligand greatly improves regioselectivity in Rh(iii) catalyzed alkene insertion/C–H activation.

Funder

National Institute of General Medical Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C4SC02590C

Reference53 articles.

1. Amide‐Directed Tandem CC/CN Bond Formation through CH Activation

2. Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

3. Multi-component syntheses of heterocycles by transition-metal catalysis

4. C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

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