Ethylene oligomerisation chromium catalysts with unsymmetrical PCNP ligands
Author:
Affiliation:
1. R & D Division
2. Sasol Technology (Pty) Ltd.
3. Sasolburg
4. South Africa
5. Department of Chemistry
6. Loughborough University
7. Loughborough
8. UK
Abstract
PCNP diphosphines, in conjunction with Cr(acac)3, are excellent ethylene oligomerisation catalysts with high activity and selectivity towards both 1-hexene and 1-octene formation.
Funder
Loughborough University
Sasol
Engineering and Physical Sciences Research Councill
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00287B
Reference54 articles.
1. Selective Ethylene Oligomerization
2. Selective ethylene oligomerization: Recent advances in chromium catalysis and mechanistic investigations
3. New processes for the selective production of 1-octene
4. Advances in selective ethylene trimerisation – a critical overview
5. Ethylene Tetramerization: A New Route to Produce 1-Octene in Exceptionally High Selectivities
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