Enantiopure cycloplatinated pentahelicenic N-heterocyclic carbenic complexes that display long-lived circularly polarized phosphorescence

Author:

Kundu Debsouri1,del Rio Natalia1,Cordier Marie1,Vanthuyne Nicolas2ORCID,Puttock Emma V.3ORCID,Meskers Stefan C. J.4ORCID,Williams J. A. Gareth3ORCID,Srebro-Hooper Monika5ORCID,Crassous Jeanne1ORCID

Affiliation:

1. Université de Rennes, CNRS, ISCR – UMR 6226, 35000 Rennes, France

2. Aix Marseille University, CNRS Centrale Marseille, iSm2, 13284 Marseille, France

3. Department of Chemistry, Durham University, Durham DH1 3LE, UK

4. Molecular Materials and Nanosystems and Institute for Complex Molecular Systems, Technische Universiteit Eindhoven, NL 5600, The Netherlands

5. Faculty of Chemistry, Jagiellonian University, Gronostajowa 2, 30-387 Krakow, Poland

Abstract

The first CPL-active square-planar Pt(ii) complexes bearing a bidentate pentahelicenic NHC ligand have been prepared and characterized.

Funder

Engineering and Physical Sciences Research Council

European Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference73 articles.

1. Stable Carbenes

2. N-Heterocyclic Carbenes: From Laboratory Curiosities to Efficient Synthetic Tools , ed. S. Díez-González , RSC , Cambridge, UK , 2011

3. An overview of N-heterocyclic carbenes

4. Chiral N-heterocyclic carbenes as stereodirecting ligands in asymmetric catalysis

5. N-Heterocyclic Carbenes in Late Transition Metal Catalysis

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