Macrocyclic Se4N2[7,7]ferrocenophane and Se2N[10]ferrocenophane containing benzyl unit: synthesis, complexation, crystal structures, electrochemical and optical properties

Author:

Qu Jian12345,Song Yinglin67894,Ji Wei123410,Jing Su1234,Zhu Dunru102114,Huang Wei52114,Zheng Mengxi121314154,Li Yanle121314154,Ma Jing121314154

Affiliation:

1. School of Chemistry and Molecular Engineering

2. Nanjing Tech University

3. Nanjing 211800

4. China

5. Institute of Advanced Materials

6. College of Physics

7. Optoelectronics and Energy

8. Soochow University

9. Suzhou 215006

10. School of Chemical Engineering

11. Nanjing 210009

12. Institute of Theoretical and Computational Chemistry

13. School of Chemistry and Chemical Engineering

14. Nanjing University

15. Nanjing 210093

Abstract

Se4N2[7,7]ferrocenophane containing benzyl unit shows switch-on third-order NLO responses to Cu2+ and Hg2+ due to the formation of delocalized π-conjugated systems.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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