Reactions of gas-phase uranyl formate/acetate anions: reduction of carboxylate ligands to aldehydes by intra-complex hydride attack-Reference-Cited by-同舟云学术

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Reactions of gas-phase uranyl formate/acetate anions: reduction of carboxylate ligands to aldehydes by intra-complex hydride attack

Published:2024 Issue:16 Volume:26 Page:12753-12763
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Bubas Amanda R.¹,Tatosian Irena J.¹,Iacovino Anna¹,Corcovilos Theodore A.²^ORCID,van Stipdonk Michael J.¹^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, Duquesne University, 600 Forbes Ave, Pittsburgh, PA 15282, USA

2. Department of Physics, Duquesne University, 600 Forbes Ave, Pittsburgh, PA 15282, USA

Abstract

Experiment and theory show that loss of acetaldehyde is favored over formaldehyde during intramolecular hydride attack in uranyl complexes with accetate and formate ligands.

Funder

Duquesne University

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D4CP00823E

Reference75 articles.

1. Electrospray Mass Spectrometry as a Technique for Elemental Analysis: Preliminary Results

2. Speciation of Uranium by Electrospray Ionization Mass Spectrometry: Comparison with Time-Resolved Laser-Induced Fluorescence

3. Can Electrospray Mass Spectrometry Quantitatively Probe Speciation? Hydrolysis of Uranyl Nitrate Studied by Gas-Phase Methods

4. Vibrational Spectroscopy of Mass-Selected [UO2(ligand)n]2+ Complexes in the Gas Phase: Comparison with Theory

5. Vibrational spectroscopy of anionic nitrate complexes of UO22+and Eu3+isolated in the gas phase

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