Cycloaddition mechanisms of CO2 and epoxide catalyzed by salophen – an organocatalyst free from metals and halides-Reference-Cited by-同舟云学术

Cycloaddition mechanisms of CO2 and epoxide catalyzed by salophen – an organocatalyst free from metals and halides

Published:2021 Issue:7 Volume:11 Page:2529-2539
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Guo Cai-Hong¹²³⁴⁵,Liang Min¹²³⁴⁵,Jiao Haijun⁶⁷⁸^ORCID

Affiliation:

1. Key Laboratory of Magnetic Molecules and Magnetic Information Materials (Ministry of Education)

2. School of Chemistry and Material Science

3. Shanxi Normal University

4. Linfen 041004

5. China

6. Leibniz-Institut für Katalyse e.V. an der Universität Rostock

7. Rostock

8. Germany

Abstract

The coupling mechanism of CO₂ and epichlorohydrin catalyzed by salophen is computed. A neutral concerted bifunctional mechanism of phenolate as nucleophile and phenol as H-bonding donor in epoxide ring-opening and CO₂ addition is suggested.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CY/D0CY02256J

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