Asymmetric 1,3-dipolar cycloaddition reactions between enals and nitrones catalysed by half-sandwich rhodium or iridium diphosphane complexes-Reference-Cited by-同舟云学术

Asymmetric 1,3-dipolar cycloaddition reactions between enals and nitrones catalysed by half-sandwich rhodium or iridium diphosphane complexes

Published:2015 Issue:4 Volume:5 Page:2460-2466
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Asenjo Ainara¹²³⁴⁵,Viguri Fernando¹²³⁴⁵,Pilar Lamata M.¹²³⁴⁵,Rodríguez Ricardo¹²³⁴⁵,Carmona María¹²³⁴⁵,Oro Luis A.¹²³⁴⁵,Carmona Daniel¹²³⁴⁵

Affiliation:

1. Departamento de Catálisis y Procesos Catalíticos

2. Instituto de Síntesis Química y Catálisis Homogénea (ISQCH)

3. CSIC - Universidad de Zaragoza

4. 50009 Zaragoza

5. Spain

Abstract

The aqua complexes [(η⁵-C₅Me₅)M(PP*)(H₂O)][SbF₆]₂(M = Rh, Ir; PP* = chiral diphosphane) catalyse the asymmetric 1,3-dipolar cycloaddition of nitrones to α,β-unsaturated aldehydes. Enantioselectivity up to 99% ee was achieved.

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CY/C4CY01533A

Reference46 articles.

1. Cycloaddition Reactions in Organic Synthesis, ed. S. Kobayashi and K. A. Jørgensen, Wiley-VCH, Weinheim, 2002

2. Iridium-Catalyzed 1,3-Dipolar Cycloadditions

3. Metal complexes versus organocatalysts in asymmetric 1,3-dipolar cycloadditions

4. Enantioselective Copper-Catalyzed 1,3-Dipolar Cycloadditions

5. Asymmetric 1,3-dipolar cycloadditions

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