Mn(iv) and Mn(v)-radical species supported by the redox non-innocent bis(2-amino-3,5-di-tert-butylphenyl)amine pincer ligand-Reference-Cited by-同舟云学术

Mn(iv) and Mn(v)-radical species supported by the redox non-innocent bis(2-amino-3,5-di-tert-butylphenyl)amine pincer ligand

Published:2017 Issue:18 Volume:53 Page:2764-2767
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Leconte Nicolas¹²³⁴,Moutet Jules¹²³⁴,Herasymchuk Khrystyna⁵⁶⁷⁸,Clarke Ryan M.⁵⁶⁷⁸,Philouze Christian¹²³⁴,Luneau Dominique⁹¹⁰¹¹⁴,Storr Tim⁵⁶⁷⁸,Thomas Fabrice¹²³⁴^ORCID

Affiliation:

1. Département de Chimie Moléculaire – Chimie Inorganique Redox (CIRE) – UMR CNRS 5250

2. UniversitéJoseph Fourier

3. 38041 Grenoble cedex 9

4. France

5. Department of Chemistry

6. Simon Fraser University

7. Burnaby

8. Canada

9. Laboratoire des Multimatériaux et Interfaces (UMR CNRS 5615)

10. Université Claude Bernard Lyon 1

11. 69622 Villeurbanne cedex

Abstract

The electron-rich pincer ligand 1 has been synthesized and chelated to manganese, affording 2 in high yield. Complex 2 comprises two iminosemiquinone radicals coordinated to a Mn(iv) ion. Its two electron oxidation produces 22+, which is a stable Mn(v)-iminosemiquinone radical complex.

Funder

Labex

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C7CC00516D

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4. Molecular and Electronic Structures of Bis-(o-diiminobenzosemiquinonato)metal(II) Complexes (Ni, Pd, Pt), Their Monocations and -Anions, and of Dimeric Dications Containing Weak Metal−Metal Bonds

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