Diphosphine-protected ultrasmall gold nanoclusters: opened icosahedral Au13 and heart-shaped Au8 clusters-Reference-Cited by-同舟云学术

Diphosphine-protected ultrasmall gold nanoclusters: opened icosahedral Au13 and heart-shaped Au8 clusters

Published:2018 Issue:5 Volume:9 Page:1251-1258
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Zhang Shan-Shan¹²³⁴⁵,Feng Lei¹²³⁴⁵,Senanayake Ravithree D.⁶⁷⁸⁹,Aikens Christine M.⁶⁷⁸⁹^ORCID,Wang Xing-Po¹²³⁴⁵,Zhao Quan-Qin¹²³⁴⁵,Tung Chen-Ho¹²³⁴⁵,Sun Di¹²³⁴⁵^ORCID

Affiliation:

1. Key Lab of Colloid and Interface Chemistry

2. Ministry of Education

3. School of Chemistry and Chemical Engineering

4. Shandong University

5. Jinan

6. Department of Chemistry

7. Kansas State University

8. Manhattan

9. USA

Abstract

Two ultrasmall gold clusters, Au₁₃ and Au₈, were identified as a distorted I_h icosahedral Au₁₃ and edge-shared “core + 4exo” structure Au₈S₂ cores, respectively. They showed interesting luminescence and electrochemical properties.

Funder

Natural Science Foundation of Shandong Province

U.S. Department of Energy

National Natural Science Foundation of China

Shandong University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C7SC03566G

Reference87 articles.