3-Cyanoallyl boronates are versatile building blocks in the synthesis of polysubstituted thiophenes-Reference-Cited by-同舟云学术

3-Cyanoallyl boronates are versatile building blocks in the synthesis of polysubstituted thiophenes

Published:2017 Issue:6 Volume:8 Page:4431-4436
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Shao Wenjie¹²³⁴⁵^ORCID,Kaldas Sherif J.¹²³⁴⁵^ORCID,Yudin Andrei K.¹²³⁴⁵^ORCID

Affiliation:

1. Davenport Research Laboratories

2. Department of Chemistry

3. University of Toronto

4. Toronto

5. Canada

Abstract

The Knoevenagel condensation between α-MIDA boryl acetaldehyde and active methylene compounds enables synthesis of novel electron-poor allylboronates and facilitates access to synthetically challenging thiophene derivatives.

Funder

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C7SC00831G

Reference72 articles.

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4. Diastereoselective Allylation of Carbonyl Compounds and Imines: Application to the Synthesis of Natural Products

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