Thermodynamic aspect of sulfur, polysulfide anion and lithium polysulfide: plausible reaction path during discharge of lithium–sulfur battery-Reference-Cited by-同舟云学术

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Thermodynamic aspect of sulfur, polysulfide anion and lithium polysulfide: plausible reaction path during discharge of lithium–sulfur battery

Published:2021 Issue:11 Volume:23 Page:6832-6840
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Tsuzuki Seiji¹²³⁴^ORCID,Kaneko Tomoaki⁵⁶⁷⁴,Sodeyama Keitaro⁵⁶⁷⁴^ORCID,Umebayashi Yasuhiro⁸⁹⁴,Shinoda Wataru¹⁰¹¹¹²⁴^ORCID,Seki Shiro¹³¹⁴¹⁵¹⁶⁴^ORCID,Ueno Kazuhide¹⁷¹⁸¹⁹⁴^ORCID,Dokko Kaoru¹⁷¹⁸¹⁹⁴²⁰^ORCID,Watanabe Masayoshi¹⁷¹⁸¹⁹⁴^ORCID

Affiliation:

1. Research Center for Computational Design of Advanced Functional Materials (CD-FMat)

2. National Institute of Advanced Industrial Science and Technology (AIST)

3. Ibaraki 305-8568

4. Japan

5. Research and Services Division of Materials Data and Integrated System

6. National Institute for Materials Science (NIMS)

7. Tsukuba

8. Graduate School of Science and Technology Niigata University 8050

9. Niigata 950-2181

10. Department of Materials Chemistry

11. Nagoya University

12. Nagoya 464-8603

13. Department of Environmental Chemistry and Chemical Engineering

14. School of Advanced Engineering

15. Kogakuin University

16. Tokyo 192-0015

17. Department of Chemistry and Biotechnology

18. Yokohama National University

19. Yokohama 240-8501

20. Unit of Elements Strategy Initiative for Catalysts & Batteries (ESICB)

Abstract

The discharge voltage of reactions for formation of Li₂S_n from S₈ is higher than that for formation of Li₂S from Li₂S_n.

Funder

Japan Society for the Promotion of Science

Advanced Low Carbon Technology Research and Development Program

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D0CP04898D

Reference42 articles.

1. A Lithium/Dissolved Sulfur Battery with an Organic Electrolyte

2. Polysulfide Shuttle Study in the Li/S Battery System

3. A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries

4. Li–O2 and Li–S batteries with high energy storage

5. Direct Measurement of Polysulfide Shuttle Current: A Window into Understanding the Performance of Lithium-Sulfur Cells

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1. Lithium polysulfide solvation and speciation in the aprotic lithium-sulfur batteries;Particuology;2024-06

2. Conformational Preference of Lithium Polysulfide Clusters Li₂S_x (x = 4–8) in Lithium–Sulfur Batteries;Inorganic Chemistry;2024-02-28

3. Enhancing Li–S Battery Performance with Limiting Li[N(SO₂F)₂] Content in a Sulfolane-Based Sparingly Solvating Electrolyte;ACS Applied Materials & Interfaces;2024-02-08

4. Linear ether-based highly concentrated electrolytes for Li–sulfur batteries;Faraday Discussions;2024

5. Polysulfides in Magnesium‐Sulfur Batteries;Advanced Materials;2023-12-03

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