Pd/CuO–Ni(OH)2/C as a highly efficient and stable catalyst for the electrocatalytic oxidation of ethanol

Author:

Zhang Sifan1,Pei An1,Li Guang2,Zhu Lihua134ORCID,Li Guoda1,Wu Fengshun1,Lin Shuting1,Chen Wenqi1,Chen Bing Hui2ORCID,Luque Rafael56ORCID

Affiliation:

1. Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry, College of Chemistry and Chemical Engineering, Faculty of Materials Metallurgy and Chemistry, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi, China

2. National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China

3. Key Laboratory of Fuel Cell Technology of Guangdong Province, South China University of Technology, Guangzhou 510640, China

4. Guangdong Provincial Key Lab of Green Chemical Product Technology, South China University of Technology, Guangzhou 510640, China

5. Departamento de Química Orgánica, Universidad de Córdoba, Campus de Rabanales, Edificio Marie Curie (C-3), Ctra Nnal IV, Km 396, E14071, Córdoba, Spain

6. Peoples Friendship University of Russia (RUDN University), 6 Miklukho Maklaya str., 117198, Moscow, Russia

Abstract

Pd/CuO-Ni(OH)2/C showed superior electrocatalytic performance for EOR in comparison with PdCuNi alloy/C and Pd/C. In-situ FTIR studies have shown that CuO and Ni(OH)2 effectively inhibited the adsorption of CO and increased the breaking rate of C-C.

Funder

Jiangxi University of Science and Technology

Guangdong Key Laboratory of Fuel Cell Technology

National Natural Science Foundation of China

RUDN University

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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